Expanding the Strained Alkyne Toolbox: Generation and Utility of Oxygen-Containing Strained Alkynes
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چکیده
منابع مشابه
Reactions of strained hydrocarbons with alkene and alkyne metathesis catalysts.
Here we describe the metathesis reactions of a strained eight-membered ring that contains both alkene and alkyne functionality. We find that the alkyne metathesis catalyst produces polymer through a ring-opening alkyne metathesis reaction that is driven by the strain release from the monomer. The strained monomer provides unusual reactivity with ruthenium-based alkene metathesis catalysts. We i...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2016
ISSN: 0002-7863,1520-5126
DOI: 10.1021/jacs.6b01986